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- W2010142844 abstract "The structure of CaMo6S8 was refined from single crystal X-ray data at 298 K (space group R3, a = 6.5146(5) Å, α = 89.63(1)°, R = 0.032 for 720 reflections with I > 3σ(I) and 25 parameters). Comparison with isoelectronic MMo6S8 (M = Yb2+, Eu2+, Sr2+, Ba2+) confirms the matrix effect predicted by J. D. Corbett (J. Solid State Chem. 39, 56 (1981)). As the cell volume increases across this series the Mo6 cluster contracts along its ternary axes by 0.021(1) Å. The strengthening of the MoMo intracluster bonds correlates with a weakening of the MoMo and MoS intercluster bonds." @default.
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- W2010142844 date "1988-03-01" @default.
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- W2010142844 title "Matrix effect in chevrel phases containing divalent metal cations. The structure of rhombohedral CaMo6S8" @default.
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