Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010143048> ?p ?o ?g. }
- W2010143048 endingPage "783" @default.
- W2010143048 startingPage "778" @default.
- W2010143048 abstract "The reaction of the ligands 1,2-bis(1,3-diisopropyl-4,5-dimethylimidazolin-2-imino)ethane (BLiPr) and 1,2-bis(1,3,4,5-tetramethylimidazolin-2-imino)ethane (BLMe) with the cycloheptatrienyl-molybdenum complex [(η7-C7H7)Mo(CH3CN)3]X (X = BF4, PF6) leads to acetonitrile substitution and formation of stable 16-electron half-sandwich complexes (η7-C7H7)Mo(BLiPr)]BF4, [1]BF4, and [(η7-C7H7)Mo(BLMe)]X, [2]X (X = BF4, PF6), two of which could be crystallographically characterized to reveal undistorted two-legged piano stool geometries. Cyclovoltammetric studies exhibit very negative redox potentials of E° = −1.095 V and E° = −1.138 V versus the ferrocene/ferrocenium couple (0 V), indicative of very electron-rich metal complexes. Oxidation of [2]X with (η7-C7H7)BF4 or [Fe(η5-C5H5)2]PF6 furnished the Mo(I) complexes of general formula [(η7-C7H7)Mo(BLMe)(CH3CN)]X2, [3]X2 (X = BF4, PF6), which display a three-legged piano stool geometry in the solid state by coordination of one additional acetonitrile molecule to molybdenum. The same geometry is observed upon reaction of [1]BF4 and [2]PF6 with 2,6-dimethylphenyl isocyanide (XyNC) to afford the isocyanide complexes [1(CNXy)]BF4 and [2(CNXy)]PF6. Their CN stretching vibrations are observed at 2041 and 2030 cm−1, confirming the electron richness and strong π-electron-releasing capability of the molybdenum-imine moiety." @default.
- W2010143048 created "2016-06-24" @default.
- W2010143048 creator A5036558577 @default.
- W2010143048 creator A5037534218 @default.
- W2010143048 creator A5062431194 @default.
- W2010143048 creator A5078539351 @default.
- W2010143048 creator A5089476171 @default.
- W2010143048 date "2008-02-01" @default.
- W2010143048 modified "2023-10-16" @default.
- W2010143048 title "Synthesis and Reactivity of 16-Electron Cycloheptatrienyl-Molybdenum(0) Complexes with Bis(imidazolin-2-imine) Ligands" @default.
- W2010143048 cites W1938652303 @default.
- W2010143048 cites W1974889964 @default.
- W2010143048 cites W1987780565 @default.
- W2010143048 cites W1993847493 @default.
- W2010143048 cites W1994617266 @default.
- W2010143048 cites W1997532416 @default.
- W2010143048 cites W2000647267 @default.
- W2010143048 cites W2003492035 @default.
- W2010143048 cites W2010396430 @default.
- W2010143048 cites W2011663526 @default.
- W2010143048 cites W2011737051 @default.
- W2010143048 cites W2011814830 @default.
- W2010143048 cites W2022081225 @default.
- W2010143048 cites W2022266802 @default.
- W2010143048 cites W2025031710 @default.
- W2010143048 cites W2033254662 @default.
- W2010143048 cites W2040438548 @default.
- W2010143048 cites W2056349155 @default.
- W2010143048 cites W2063074480 @default.
- W2010143048 cites W2063232168 @default.
- W2010143048 cites W2064590361 @default.
- W2010143048 cites W2066203843 @default.
- W2010143048 cites W2074146676 @default.
- W2010143048 cites W2079252964 @default.
- W2010143048 cites W2081335056 @default.
- W2010143048 cites W2083701940 @default.
- W2010143048 cites W2083823893 @default.
- W2010143048 cites W2085755442 @default.
- W2010143048 cites W2086324115 @default.
- W2010143048 cites W2089661702 @default.
- W2010143048 cites W2098702268 @default.
- W2010143048 cites W2101049266 @default.
- W2010143048 cites W2103702108 @default.
- W2010143048 cites W2104884367 @default.
- W2010143048 cites W2107927722 @default.
- W2010143048 cites W2135901811 @default.
- W2010143048 cites W2137039936 @default.
- W2010143048 cites W2139729923 @default.
- W2010143048 cites W2167828937 @default.
- W2010143048 cites W2202948104 @default.
- W2010143048 cites W2950230733 @default.
- W2010143048 cites W2952684558 @default.
- W2010143048 cites W4236581815 @default.
- W2010143048 cites W51038543 @default.
- W2010143048 doi "https://doi.org/10.1021/om700953u" @default.
- W2010143048 hasPublicationYear "2008" @default.
- W2010143048 type Work @default.
- W2010143048 sameAs 2010143048 @default.
- W2010143048 citedByCount "34" @default.
- W2010143048 countsByYear W20101430482013 @default.
- W2010143048 countsByYear W20101430482014 @default.
- W2010143048 countsByYear W20101430482015 @default.
- W2010143048 countsByYear W20101430482016 @default.
- W2010143048 countsByYear W20101430482019 @default.
- W2010143048 countsByYear W20101430482022 @default.
- W2010143048 countsByYear W20101430482023 @default.
- W2010143048 crossrefType "journal-article" @default.
- W2010143048 hasAuthorship W2010143048A5036558577 @default.
- W2010143048 hasAuthorship W2010143048A5037534218 @default.
- W2010143048 hasAuthorship W2010143048A5062431194 @default.
- W2010143048 hasAuthorship W2010143048A5078539351 @default.
- W2010143048 hasAuthorship W2010143048A5089476171 @default.
- W2010143048 hasConcept C142724271 @default.
- W2010143048 hasConcept C147789679 @default.
- W2010143048 hasConcept C155647269 @default.
- W2010143048 hasConcept C161790260 @default.
- W2010143048 hasConcept C17525397 @default.
- W2010143048 hasConcept C178790620 @default.
- W2010143048 hasConcept C179104552 @default.
- W2010143048 hasConcept C185592680 @default.
- W2010143048 hasConcept C204787440 @default.
- W2010143048 hasConcept C2776568683 @default.
- W2010143048 hasConcept C2776573223 @default.
- W2010143048 hasConcept C2776910235 @default.
- W2010143048 hasConcept C2777010268 @default.
- W2010143048 hasConcept C2777237805 @default.
- W2010143048 hasConcept C2777463227 @default.
- W2010143048 hasConcept C2779240715 @default.
- W2010143048 hasConcept C32909587 @default.
- W2010143048 hasConcept C52859227 @default.
- W2010143048 hasConcept C549387045 @default.
- W2010143048 hasConcept C71240020 @default.
- W2010143048 hasConcept C71924100 @default.
- W2010143048 hasConcept C8010536 @default.
- W2010143048 hasConceptScore W2010143048C142724271 @default.
- W2010143048 hasConceptScore W2010143048C147789679 @default.
- W2010143048 hasConceptScore W2010143048C155647269 @default.
- W2010143048 hasConceptScore W2010143048C161790260 @default.