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- W2010147313 abstract "Abstract The strong solvent polarity dependence observed in the nonradiative decay rates of Bis[4-(dimethylamino)phenyl]squaraine (SQ-DMA) had previously been explained by the twisted intramolecular charge transfer mechanism. However, our recent theoretical study did not support this mechanism. We theoretically study the possibility of electron-driven proton transfer (EDPT) processes between an alcohol solvent molecule and the CO − groups of SQ-DMA using a complex model. The results actually support the EDPT mechanism that proceeds via two nonadiabatic transitions: the first from the locally excited (π → π*) state of SQ-DMA to the charge transfer (CT) state, and the second from the CT to S 0 states." @default.
- W2010147313 created "2016-06-24" @default.
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- W2010147313 date "2015-04-01" @default.
- W2010147313 modified "2023-09-24" @default.
- W2010147313 title "A two-step electron-driven proton transfer mechanism for the solution-phase nonradiative decay process of squaraine molecule" @default.
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- W2010147313 doi "https://doi.org/10.1016/j.cplett.2015.02.025" @default.
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