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- W2010168642 abstract "EHT calculations have been performed on model molecules acting as substrates for mammalian mono-oxygenases. CαH bonds are consistently found to have larger overlap populations compared with CβH and CγH bonds. It is known on the other hand that metabolic hydroxylation of aliphatic carbon atoms shows a marked regioselectivity for α-carbons. The quantum-mechanical results sustain the view that CH bonds of relatively high electronic density are preferred target sites for the cytochrome P-450-mediated oxygenation, and that the oxygen atom being activated is transformed into an electrophilic species capable of CH bond insertion." @default.
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- W2010168642 date "1978-02-01" @default.
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- W2010168642 title "Regioelectronic factors in metabolic hydroxylation of aliphatic carbon atoms" @default.
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- W2010168642 doi "https://doi.org/10.1016/0022-5193(78)90247-3" @default.
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