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• W2010170568 endingPage "1124" @default.
• W2010170568 startingPage "1116" @default.
• W2010170568 abstract "We investigate a two-component acid-amine gelation system in which chirality plays a vital role. A carboxylic acid based on a second generation l-lysine dendron interacts with chiral amines and subsequently assembles into supramolecular gel fibers. The chirality of the amine controls the assembly of the resulting diastereomeric complexes, even if this chirality is relatively poor quality. Importantly, the selective incorporation of one enantiomer of an amine over the other into the gel network has been demonstrated, with the R amine that forms complexes which assemble into the most stable gel being primarily selected for incorporation. Thermodynamic control has been proven by forming a gel exclusively with an S amine, allowing the R enantiomer to diffuse through the gel network, and displacing it from the solidlike fibers, demonstrating that these gels adapt and evolve in response to chemical stimuli to which they are exposed. Excess amine, which remains unincorporated within the solidlike gel fiber network, can diffuse out and be reacted with an isocyanate, allowing us to quantify the enantioselectivity of component selection but also demonstrating how gels can act as selective reservoirs of potential reagents, releasing them on demand to undergo further reactions; hence, component-selective gel assembly can be coupled with controlled reactivity." @default.
• W2010170568 created "2016-06-24" @default.
• W2010170568 creator A5038105291 @default.
• W2010170568 creator A5081425132 @default.
• W2010170568 date "2014-01-08" @default.
• W2010170568 modified "2023-09-24" @default.
• W2010170568 title "Enantioselective Component Selection in Multicomponent Supramolecular Gels" @default.
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• W2010170568 doi "https://doi.org/10.1021/ja411724r" @default.
• W2010170568 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24400807" @default.
• W2010170568 hasPublicationYear "2014" @default.
• W2010170568 type Work @default.
• W2010170568 sameAs 2010170568 @default.

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