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- W2010177814 abstract "In the title compound, C24H20FN3O2, despite the 4H-pyran ring having a flattened half-chair conformation [the methine C atom lies 0.257 (3) Å above the plane of the remaining atoms with an r.m.s. deviation of 0.0295 Å], the 14 non-H atoms of the 4H-benzo[h]chromene residue are approximately coplanar (r.m.s. deviation = 0.081 Å). The benzene ring is nearly perpendicular to this plane [dihedral angle = 76.18 (10)°], but the planar (r.m.s. deviation = 0.033 Å) dimethylmethanimidamide substituent is coplanar [dihedral angle = 1.96 (12)°]. In the crystal, centrosymmetric dimeric aggregates arise from C—H⋯N interactions, and these are connected into supramolecular layers in the ab plane by C—H⋯π and π–π [intercentroid (central C6 ring)⋯(outer C6 ring)i distance = 3.8564 (14) Å] interactions." @default.
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- W2010177814 date "2013-03-02" @default.
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- W2010177814 title "<i>N</i>′-[3-Cyano-4-(4-fluorophenyl)-6-methoxy-4<i>H</i>-benzo[<i>h</i>]chromen-2-yl]-<i>N</i>,<i>N</i>-dimethylmethanimidamide" @default.
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- W2010177814 doi "https://doi.org/10.1107/s1600536813005503" @default.
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