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• W2010185038 abstract "The reaction of Mes2CC(OH)SiMe2R (RMe, SiMe3) with SOCl2 gives the rearranged elimination product MesCCMes, presumably via β-mesityl participation in the solvolysis of the derived OSOCl derivative, followed by “Me3Si+“ loss from the rearranged ion MesC(Me3Si)C-Mes. Under the same conditions, the carbon analogue Mes2CC(OH)Bu-t gives the ketone Mes2CHCOBu-t and benzofurans via non-solvolytic reactions." @default.
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• W2010185038 date "1991-10-01" @default.
• W2010185038 modified "2023-09-25" @default.
• W2010185038 title "A rearranged acetylene from an E1 solvolysis of a substituted α-trimethylsilylvinyl system" @default.
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• W2010185038 doi "https://doi.org/10.1016/0040-4039(91)80177-8" @default.
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