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- W2010189672 abstract "Compounds that contain an unbridged WW bond can be prepared through bimolecular decomposition of various imido alkylidene complexes. One type of WW species is [W(NR)(CH2-t-Bu)(OR‘)]2 (R = 2,6-dimethylphenyl (Ar‘) or 2,6-diisopropylphenyl (Ar); R‘ = pentafluorophenyl or hexafluoroisopropyl), which is found in both heterochiral and homochiral forms. The other type is [W(NR)(OR‘)2]2 (R‘ = trifluoro-tert-butyl or hexafluoro-tert-butyl). All species contain an unbridged W(IV)/W(IV) double bond with a WW bond distance of 2.4−2.5 Å, a 90° angle between the imido ligands and the WW bond, and an anti relationship of the imido ligands. There is no indication that WW bonds are broken spontaneously; for example, heterochiral and homochiral [W(NR)(CH2-t-Bu)(OR‘)]2 species do not interconvert." @default.
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- W2010189672 date "2006-03-14" @default.
- W2010189672 modified "2023-10-09" @default.
- W2010189672 title "Dimers that Contain Unbridged W(IV)/W(IV) Double Bonds" @default.
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- W2010189672 doi "https://doi.org/10.1021/om050961s" @default.
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