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- W2010200416 abstract "A new complex {[Co(hfac)2]2(4P3NIT)2}·CHCl3 (1) (hfac: hexafluoroacetylacetonate, 4P3NIT: 2-[3-(4-pyridyl)phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been synthesized and characterized structurally and magnetically. The single-crystal structure revealed that two 4P3NIT molecules and two [Co(hfac)2] units construct a four-spin rectangle-like molecule. Effective-spin approach was also employed to evaluate the magnetic coupling J1 and J2 within this four-spin unit. The best fitting result gives J1 = −23.41 cm−1, J2 = 3.18 cm−1, which indicate the antiferromagnetic interaction between the Co(II) ion and directly bonded radical, and weak ferromagnetic interaction between the central Co(II) ion and organic radical through the pathway of pyridyl and phenyl ring." @default.
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- W2010200416 date "2012-11-05" @default.
- W2010200416 modified "2023-10-16" @default.
- W2010200416 title "A Four-spin Cobalt-radical Complex: Structure and Magnetic Properties" @default.
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- W2010200416 doi "https://doi.org/10.1246/cl.2012.1523" @default.
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