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- W2010202455 abstract "Abstract The uncommon sodium rare-earth phosphate mineral vitusite-(Ce) (Na 3 RE (PO 4 ) 2 ) can be considered as the extreme product of sodium and rare-earth substitution in the apatite structure. Lesser amounts of substitution provide sodium and rare-earth-bearing apatites up to about 80 mol.% exchange; beyond this point vitusite is the stable phase. The structure of vitusite, determined previously from a synthetic analogue, can also be considered as a derivative from apatite, but with cations exchanged on sites normally occupied by anions. Vitusite can therefore be considered as a sodium- and rare-earthrich apatite end-member, with a distinct, but apatite-derived, structure, formed in highly persodic and high rare-earth environments. From an examination of the literature on diffusion in apatite, vitusite in principle could be formed from apatite sensu stricto by subsolidus diffusion in response to late-stage Naand RE -rich hydrothermal fluids." @default.
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- W2010202455 date "1992-06-01" @default.
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- W2010202455 title "Vitusite — an apatite derivative structure" @default.
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- W2010202455 doi "https://doi.org/10.1180/minmag.1992.056.383.10" @default.
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