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- W2010215464 abstract "The reaction of chlorine with alkaline hydrogen peroxide has been used to produce O 2 ( a 1 Δ g ) in a fast flow system at partial pressures up to about 0.5 Torr, and total pressures (mostly argon) in the range 0.8–2.5 Torr. Absolute concentrations of O 2 ( a 1 Δ g ) were determined from the intensity of absorption of hydrogen emission lines in the vacuum-UV at 144.095 and 148.66 nm, for which the cross sections are known. The intensity of the O 2 ( a → X) transition at 1270 nm, monitored simultaneously with a simple germanium detector, was found to vary linearly with [O 2 ( a 1 Δ g )], as expected. The germanium detector was calibrated at 1270 nm with a readily reproducible standard, the air afterglow continuum due to NO 2 * at defined concentrations of O( 3 P) and NO. The ratio of k a for O 2 ( a) k a O 2 ( X) + hv t to k c for O + NO k c NO 2 + hv, is (1.4 ± 0.2) × 10 −7 mol L −1 at 1270 nm." @default.
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- W2010215464 date "1986-02-01" @default.
- W2010215464 modified "2023-09-27" @default.
- W2010215464 title "A Spectrometric Technique for Monitoring [O2(a1 Δg)] in the Gas Phase" @default.
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- W2010215464 doi "https://doi.org/10.1366/0003702864509411" @default.
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