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- W2010224630 endingPage "7844" @default.
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- W2010224630 abstract "We have developed an efficient method for the synthesis of benzimidazoles via cascade reactions of o-haloacetoanilide derivatives with amidine hydrochlorides. The protocol uses 10 mol % CuBr as the catalyst, Cs2CO3 as the base, and DMSO as the solvent, and no ligand is required. The procedure proceeds via the sequential coupling of o-haloacetoanilide derivatives with amidines, hydrolysis of the intermediates (amides), and intramolecular cyclization with the loss of NH3 to give 2-substituted 1H-benzimidazoles." @default.
- W2010224630 created "2016-06-24" @default.
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- W2010224630 date "2008-08-28" @default.
- W2010224630 modified "2023-10-07" @default.
- W2010224630 title "Copper-Catalyzed Synthesis of Benzimidazoles via Cascade Reactions of <i>o</i>-Haloacetanilide Derivatives with Amidine Hydrochlorides" @default.
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- W2010224630 doi "https://doi.org/10.1021/jo8014984" @default.
- W2010224630 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18754576" @default.
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