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• W2010230379 abstract "The degradation of a polyacetylene (PA) anode as proposed in PAy+ (ClO)y/LiClO4/PC type half cells has been investigated by resonant Raman scattering. – During electrochemical cycling, which modelled the operation of a PA/Li cell as a rechargeable storage battery, degradation becomes evident after only a few cycles. The charge regainable in the reduction steps after the seventh step is only 80 percent of the charge transferred in the preceding oxidation step. – The resonance Raman spectra have been analysed according to the method of Kuzmany which yields informations on the length distribution of conjugated segments in the sample. At the beginning of cycling a distribution of long segments and a distribution peaked at segment lengths around 5 double bonds have been found to coexist. After 7 cycles the long segments are already affected by the degradation and after a total of 27 cycles the Raman spectrum reveals the complete absence of conjugated segments longer than 10 double bonds." @default.
• W2010230379 created "2016-06-24" @default.
• W2010230379 creator A5060413144 @default.
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• W2010230379 date "1984-10-01" @default.
• W2010230379 modified "2023-09-26" @default.
• W2010230379 title "A Resonance Raman Investigation on the Degradation of Polyacetylene During Electrochemical Cycling" @default.
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• W2010230379 doi "https://doi.org/10.1002/bbpc.19840881004" @default.
• W2010230379 hasPublicationYear "1984" @default.
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