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- W2010241014 abstract "The vibrational frequencies of halogens adsorbed on Ag(100) are calculated. The frequency of a single adsorbed atom vibration perpendicular to the surface is obtained from AgX (X=F, Cl, Br, I) crystal frequencies. Interaction between dipoles consisting of the effective charge on the adsorbed atom and its induced image charge produces a coverage dependent frequency. The effective charge on the adsorbed atom is assumed to be 1.0e, while the electronic polarizability of the real-plus-image atom system is assumed to be twice the electronic polarizability of X−. At full coverage, the calculated frequencies for the k=0 modes are 437, 241, 150, and 113 cm−1, respectively, for X=F, Cl, Br, I, which compare well with experimental values, and these frequencies are assigned to external vibrational model of halogen atoms adsorbed on silver." @default.
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- W2010241014 date "1981-02-01" @default.
- W2010241014 modified "2023-09-23" @default.
- W2010241014 title "Vibrational frequencies of halogen atoms adsorbed on silver metal surfaces" @default.
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- W2010241014 doi "https://doi.org/10.1063/1.441252" @default.
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