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- W2010241810 abstract "AuCl and (CH3)2AuCl complexes of the following series of azaphospholes have been prepared and characterized by analytical and spectroscopic data: 2,5-dimethyl-1,2,3-diazaphosphole (1), 5-methyl-2-phenyl-1,2,3-diazaphosphole (2), 2-methyl-5-phenyl-1,2,4,3-triazaphosphole (3), and 1,5-dimethyl-1,2,4,3-triazaphosphole (4). The (CH3)2AuCl complexes are assigned a planar cis-structure with P-coordination for 2 and 3, but N-coordination for 1 and 4. Imidazole forms a 1:1 complex with (CH3)2AuCl (9), but a 2:1 complex with AuCl (10). Low solubilities of the 1:1 complexes of AuCl with the azaphospholes preclude detailed structure analyses in solution. The complexes are of interest for pharmacological studies." @default.
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- W2010241810 title "N- or P-coordination in Di- and triazaphosphole gold complexes" @default.
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- W2010241810 doi "https://doi.org/10.1016/s0020-1693(00)84186-9" @default.
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