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- W2010258231 abstract "Abstract 3, 3′-[l, 3-Phenylenebis(methylene)]bis(2, 4-pentanedione) (H2L) was prepared by the reaction of 2, 4-pentanedione and 1, 3-bis (bromomethyl) benzene. From a ratio of the intensities of the 1H n. m. r. spectrum, the keto form of H2L is about 87% and the enol form is about 13% The dicopper(II) complex (Cu2L2) of H2L was prepared. A strong i.r. band due to the C=O stretching mode is shifted toward lower energy upon the production of Cu2L2 complex. The ligand field spectrum of Cu2L2 complex is similar to that for bis(2, 4-pentanedionato)copper(II) complex and the copper atom has primarily the square-planar coordination. As judged by the e.s.r. spectra, Cu2L2 complex is the cofacial bimetallic system." @default.
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- W2010258231 date "1991-02-01" @default.
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- W2010258231 title "Preparation and Spectroscopic Properties of Cofacial Binuclear Copper(II) Complex with 3, 3′-[1,3-Phenylene-bis(methylene)]bis(2,4-pentanedione)" @default.
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- W2010258231 doi "https://doi.org/10.1080/15533179108020174" @default.
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