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- W2010263078 abstract "The pH dependence of acetate coordination of Zn-, Cd- and Hg-CyDTA (cyclohexane-diaminetetraacetate) complexes and the nitrogen inversion of Ca-, Sr and Ba-CyDTA complexes was studied by 1H NMR. It was shown that the electron density on the out-of-plane coordinated carboxyl oxygens was more than that on the in-plane ones for Zn- and Hg-CyDTA, while no distinct difference of the electron density between the out-of-plane and in-plane coordinated carboxyl oxygens was observed for Cd-CyDTA. It was found that in the nitrogen inversion of Ca-, Sr- and Ba-CyDTA both H+ and OH− in solution would help the dissociation of the metal-nitrogen bond and decrease the activation energy of the process." @default.
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- W2010263078 title "pH dependence of acetate coordination and intramolecular rearrangement of CyDTA metal complexes—1H NMR study" @default.
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- W2010263078 doi "https://doi.org/10.1016/s0277-5387(97)00084-3" @default.
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