Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010272590> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2010272590 endingPage "78" @default.
- W2010272590 startingPage "65" @default.
- W2010272590 abstract "Several grams of labelled trans linoleic and linolenic acids with high chemical and isomeric purities (>97%) have been prepared for human metabolism studies. A total of 12.5 g of (9Z, 12E)-[1-(13)C]-octadeca-9,12-dienoic acid and 6.3 g of (9Z,12Z, 15E)-[1-(13)C]-octadeca-9,12,15-trienoic acid were obtained in, respectively, seven steps (7.8% overall yield) and 11 steps (7% overall yield) from 7-bromo-heptan-1-ol. The trans bromo precursors used for the labelling were synthesised by using copper-catalysed couplings. The trans fatty acids were then obtained via the nitrile derivatives. A total of 23.5 g of (9Z,12Z)-[1-(13)C]-octadeca-9, 12-dienoic acid and 10.4 g of (9Z,12Z,15Z)-[1-(13)C]-octadeca-9,12, 15-trienoic acid were prepared in five steps in, respectively, 32 and 18% overall yield. Large quantities of bromo and chloro precursors were synthesised from the commercially available acid according to Barton's procedure. In all cases, the main impurities (>0.5%) of each labelled fatty acid have been characterised." @default.
- W2010272590 created "2016-06-24" @default.
- W2010272590 creator A5009206632 @default.
- W2010272590 creator A5018305414 @default.
- W2010272590 creator A5041986914 @default.
- W2010272590 creator A5052635600 @default.
- W2010272590 creator A5073479284 @default.
- W2010272590 creator A5084859817 @default.
- W2010272590 creator A5087622240 @default.
- W2010272590 date "2000-06-01" @default.
- W2010272590 modified "2023-10-18" @default.
- W2010272590 title "Large-scale preparation of (9Z,12E)-[1-13C]-octadeca-9,12-dienoic acid, (9Z,12Z,15E)-[1-13C]-octadeca-9,12,15-trienoic acid and their [1-13C] all-cis isomers" @default.
- W2010272590 cites W1965881474 @default.
- W2010272590 cites W1973107708 @default.
- W2010272590 cites W1974945762 @default.
- W2010272590 cites W1978230394 @default.
- W2010272590 cites W1981206147 @default.
- W2010272590 cites W1981441053 @default.
- W2010272590 cites W1987947113 @default.
- W2010272590 cites W1988018706 @default.
- W2010272590 cites W2006942758 @default.
- W2010272590 cites W2011491667 @default.
- W2010272590 cites W2011936602 @default.
- W2010272590 cites W2028248238 @default.
- W2010272590 cites W2044880427 @default.
- W2010272590 cites W2053856517 @default.
- W2010272590 cites W2054827299 @default.
- W2010272590 cites W2059063320 @default.
- W2010272590 cites W2082904759 @default.
- W2010272590 cites W2083519636 @default.
- W2010272590 cites W2085278225 @default.
- W2010272590 cites W2087870597 @default.
- W2010272590 cites W2090189176 @default.
- W2010272590 cites W2129243500 @default.
- W2010272590 cites W2142768834 @default.
- W2010272590 cites W2326877893 @default.
- W2010272590 cites W2340147094 @default.
- W2010272590 cites W2462104485 @default.
- W2010272590 cites W2951790825 @default.
- W2010272590 cites W2952603728 @default.
- W2010272590 doi "https://doi.org/10.1016/s0009-3084(00)00137-7" @default.
- W2010272590 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10878236" @default.
- W2010272590 hasPublicationYear "2000" @default.
- W2010272590 type Work @default.
- W2010272590 sameAs 2010272590 @default.
- W2010272590 citedByCount "17" @default.
- W2010272590 countsByYear W20102725902012 @default.
- W2010272590 countsByYear W20102725902013 @default.
- W2010272590 countsByYear W20102725902014 @default.
- W2010272590 countsByYear W20102725902017 @default.
- W2010272590 countsByYear W20102725902020 @default.
- W2010272590 countsByYear W20102725902021 @default.
- W2010272590 countsByYear W20102725902023 @default.
- W2010272590 crossrefType "journal-article" @default.
- W2010272590 hasAuthorship W2010272590A5009206632 @default.
- W2010272590 hasAuthorship W2010272590A5018305414 @default.
- W2010272590 hasAuthorship W2010272590A5041986914 @default.
- W2010272590 hasAuthorship W2010272590A5052635600 @default.
- W2010272590 hasAuthorship W2010272590A5073479284 @default.
- W2010272590 hasAuthorship W2010272590A5084859817 @default.
- W2010272590 hasAuthorship W2010272590A5087622240 @default.
- W2010272590 hasConcept C134121241 @default.
- W2010272590 hasConcept C178790620 @default.
- W2010272590 hasConcept C185592680 @default.
- W2010272590 hasConcept C191897082 @default.
- W2010272590 hasConcept C192562407 @default.
- W2010272590 hasConcept C2780809830 @default.
- W2010272590 hasConcept C543025807 @default.
- W2010272590 hasConcept C71240020 @default.
- W2010272590 hasConceptScore W2010272590C134121241 @default.
- W2010272590 hasConceptScore W2010272590C178790620 @default.
- W2010272590 hasConceptScore W2010272590C185592680 @default.
- W2010272590 hasConceptScore W2010272590C191897082 @default.
- W2010272590 hasConceptScore W2010272590C192562407 @default.
- W2010272590 hasConceptScore W2010272590C2780809830 @default.
- W2010272590 hasConceptScore W2010272590C543025807 @default.
- W2010272590 hasConceptScore W2010272590C71240020 @default.
- W2010272590 hasIssue "1" @default.
- W2010272590 hasLocation W20102725901 @default.
- W2010272590 hasLocation W20102725902 @default.
- W2010272590 hasLocation W20102725903 @default.
- W2010272590 hasOpenAccess W2010272590 @default.
- W2010272590 hasPrimaryLocation W20102725901 @default.
- W2010272590 hasRelatedWork W1967096148 @default.
- W2010272590 hasRelatedWork W1982983244 @default.
- W2010272590 hasRelatedWork W1984189444 @default.
- W2010272590 hasRelatedWork W1996103846 @default.
- W2010272590 hasRelatedWork W2018223387 @default.
- W2010272590 hasRelatedWork W2047223968 @default.
- W2010272590 hasRelatedWork W2354901943 @default.
- W2010272590 hasRelatedWork W2414705096 @default.
- W2010272590 hasRelatedWork W2432662585 @default.
- W2010272590 hasRelatedWork W4302076097 @default.
- W2010272590 hasVolume "106" @default.
- W2010272590 isParatext "false" @default.
- W2010272590 isRetracted "false" @default.
- W2010272590 magId "2010272590" @default.
- W2010272590 workType "article" @default.