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- W2010277829 abstract "The base peak in the mass spectrum of several 1,4,2-benzoxazinone derivatives 1a–f (cf. Scheme 1 and the Table) suggests a clean carbon monoxide elimination leading to benzoxazole radical cations 2a–f. This benzoxazinone-benzoxazole conversion can be reproduced quantitatively by flash vacuum thermolysis. The isomeric 2,4,1-benzoxazinone 4 (cf. Scheme 2) eliminates carbon dioxide – the resulting biradical species 5 does not recombine to benzazete 10 but fragments into nitrile and benzyne (7)." @default.
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- W2010277829 date "1977-01-26" @default.
- W2010277829 modified "2023-09-28" @default.
- W2010277829 title "The Thermal Benzoxazinone-Benzoxazole Conversion, a Reexecution of a Mass Spectrometric Decay by Thermolysis" @default.
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- W2010277829 doi "https://doi.org/10.1002/hlca.19770600121" @default.
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