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• W2010292511 abstract "The infrared spectrum of HSiD3 has been recorded with a resolution of 3.3 × 10−3 cm−1 in the 600–775 cm−1 region. The fundamentals ν3 (A1), ν0 = 675.501 cm−1, and ν6 (E), ν0 = 682.687 cm−1 have been measured and rotationally assigned up to J′ = 30. Owing to the closeness of the band centers and the strength of the x, y-Coriolis interaction, ζy36 = 0.62, perturbations both of positions and intensities are strong. Since HSiD3 is an oblate top near the spherical top limit, the rotational energy level structure is such that numerous avoided crossings with Δ(k − l) = ±3 and ±6 are called forth by the Coriolis resonance. These give rise to “forbidden” transitions, 209 of which with J and K ≤ 30, and ΔK up to ±6, were observed. These enabled a significant improvement of the coefficients of the K-dependent ground state energy terms, C0 = 1.433 4268(12)cm−1, D0K = 2.851 6(57) × 10−6 cm−1, and H0K = −1.728(85) × 10−10 cm−1. Parameters of the v3 = 1 and v6 = 1 excited states were determined with two models corresponding to two different effective Hamiltonians. The model strictly obeying the constraints proposed by E. I. Lobodenko, O. N. Sulakshina, V. I. Perevalov, and V. G. Tyuterev (J. Mol. Spectrosc. 126, 159–170 (1987)) requires 45 adjustable parameters and fits the data with J ≥ 22 only poorly while, with an alternative model employing 44 free parameters, all data up to J′ = 30 were fitted with ς = 1.72 × 10−4 cm−1. A positive sign of the Coriolis intensity perturbation was found, and the transition moment ratio was determined, ‖M6:M3‖ = 0.70(5)." @default.
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• W2010292511 date "2000-07-01" @default.
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• W2010292511 title "The Near Degenerate ν3 and ν6 States of HSiD3 Revealing Δ(k − l) = 0, ±3, and ±6 Interactions" @default.
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• W2010292511 doi "https://doi.org/10.1006/jmsp.2000.8100" @default.
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