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• W2010295511 startingPage "4753" @default.
• W2010295511 abstract "Lattice parameters of solid xenon have been measured at sublimation in the temperature range 78.2-160.7 K and at melting in the range 161.7-216.0 K. From these precise data, information about (1) thermal expansion and thermal vacancies and (2) thermodynamic and equation-of-state properties can be obtained. Analysis of the sublimation data yields the first determination of the x-ray coefficient of thermal expansion ${ensuremath{beta}}_{x}$ in the regime where thermal vacancies are numerous. Comparison of ${ensuremath{beta}}_{x}$ with the coefficient of bulk thermal expansion allows the first experimental determination of the vacancy formation parameters in solid xenon. As is the case for krypton, a significant discrepancy is found between the experimental vacancy formation enthalpy and published theoretical estimates. To obtain thermodynamic and equation-of-state information, the present sublimation and melting lattice parameters are used in conjunction with previously determined sublimation and melting pressures. These data are analyzed to calculate the parameters ${(frac{ensuremath{partial}P}{ensuremath{partial}T})}_{V}$, ${(frac{ensuremath{partial}{B}_{T}}{ensuremath{partial}T})}_{V}$, and ${ensuremath{chi}}_{T,x}$, the x-ray isothermal compressibility, with a substantial improvement in accuracy over those obtained by purely macroscopic means." @default.
• W2010295511 created "2016-06-24" @default.
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• W2010295511 date "1981-10-15" @default.
• W2010295511 modified "2023-09-26" @default.
• W2010295511 title "Crystalline xenon: Lattice parameters, thermal expansion, thermal vacancies, and equation of state" @default.
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• W2010295511 doi "https://doi.org/10.1103/physrevb.24.4753" @default.
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