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- W2010306033 abstract "A method for the facile synthesis of tetraaryl-trimethylsilylmethyl-hydro[60]fullerenes, C 60 Ar 4 (CH 2 SiMeR)H, has been developed in which readily prepared anionic mono(silylmethyl) fullerene is subjected to reaction conditions for organocopper-mediated multiple addition. Penta(organo)fullerene derivatives bearing different substituents and diverse functionality were synthesized in moderate to good yield under simple and mild reaction conditions. Further organic and organometallic transformations of these fullerenes allowed us to synthesize transition-metal complexes and a new methanofullerene derivative, 1,9-methano-6,12,15,18-tetraphenyl[60]fullerene, C 60 Ph 4 (CH 2 )." @default.
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- W2010306033 date "2011-12-01" @default.
- W2010306033 modified "2023-09-24" @default.
- W2010306033 title "Regioselective synthesis of tetra(aryl)-mono(silylmethyl)[60]fullerenes and derivatization to methanofullerene compound" @default.
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- W2010306033 doi "https://doi.org/10.1016/j.tet.2011.09.125" @default.
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