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- W2010328083 abstract "In contrast with dibenzo[24]crown-8 (DB24C8), when tetrabenzo[24]crown-8 (TB24C8) is mixed with dibenzylammonium hexafluorophosphate (DBA·PF6) in noncompetitive solvents, the thermodynamically driven noncovalent synthesis of the threaded 1:1 complexa [2]pseudorotaxanedoes not occur. However, on crystallization from solutionin a process which is presumably kinetically controlledTB24C8 molecules and DBA+ cations form an array of [2]pseudorotaxanes stabilized by a plethora of [C−H···F] hydrogen bonds to highly ordered, interstitially located PF6- anions." @default.
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- W2010328083 date "1999-11-16" @default.
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- W2010328083 title "Anion-Orchestrated Formation in the Crystalline State of [2]Pseudorotaxane Arrays" @default.
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- W2010328083 doi "https://doi.org/10.1021/ol991089k" @default.
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