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• W2010338001 abstract "Time-resolved vibrational chemiluminescence from HF has been recorded following the production of F atoms by the pulsed laser photolysis (λ = 266 nm) of F2 in the presence of HCl, CH4, and CF3H. In the first two cases, experiments have been conducted by observing emission from HF(ν = 3) at four temperatures from 295 to 139 K. Rate constants have been determined over this range of temperature for the reactions of F atoms with HCl and CH4 and of CH3 radicals with F2, and for the relaxation of HF(ν = 3) by HCl and CH4. The reaction of F atoms with CF3H is slower than those with HCl and CH4 and measurements on the emission from HF(ν = 2) have been used to infer rate constants for reaction and relaxation only at 295 K. © 1994 John Wiley & Sons, Inc." @default.
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• W2010338001 date "1994-08-01" @default.
• W2010338001 modified "2023-09-25" @default.
• W2010338001 title "Rates of processes initiated by pulsed laser production of F atoms in the presence of HCl, CH4, and CF3H" @default.
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• W2010338001 doi "https://doi.org/10.1002/kin.550260804" @default.
• W2010338001 hasPublicationYear "1994" @default.
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