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- W2010351190 abstract "ENDOR measurements and covalency arguments have been used to investigate the electron distribution in CsCdF 3 crystals containing Mn 2+ and Ni 2+ . The bond structure is of the form M—F − —Cd 2+ (M = Mn 2+ or Ni 2+ ) and the measured isotropic supertransferred hyperfine interaction (sthfi) at the Cd site is related to the unpaired spin fraction f σ in the 2p σ orbital of F − by three different theoretical approximations. In these three methods it is assumed that [Formula: see text] orbital of the 3d ion, and the 2p z orbital of the F − ion make eovalent bonds with the (4s), (3s,4s,5s), and (1s,2s,3s,4s,5s) sets of orbitals of the Cd 2+ ion respectively. The results show that cadmium core s electrons make important contributions to the isotropic sthfi. However, it seems that f σ values obtained are fairly insensitive to the approximations used." @default.
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- W2010351190 date "1982-05-01" @default.
- W2010351190 modified "2023-10-16" @default.
- W2010351190 title "The effect of core electrons on the spin transfer parameters" @default.
- W2010351190 doi "https://doi.org/10.1139/p82-086" @default.
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