Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010381158> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2010381158 abstract "The effects of relativity on the magnetic-field induced circular birefringence, or Faraday effect, in He, Ne, Ar, Xe, Rn, F2, Cl2, Br2, and I2 have been determined at the four-component Hartree-Fock level of theory. A measure of the birefringence is given by the Verdet constant, which is a third-order molecular property and thus relates to quadratic response functions. A fully analytical nonlinear polarization propagator approach is employed. The results are gauge invariant as a consequence of the spatial symmetries in the molecular systems. The calculations include electronic as well as vibrational contributions to the property. Comparison with experiment is made for He, Ne, Ar, Xe, and Cl2, and, apart from neon, the theoretical values of the Verdet constant are within 10% of the experimental ones. The inclusion of nonrelativistically spin-forbidden excitations in the propagator parametrization has significant effects on the dispersion in general, but such effects are in the general case largely explained by the use of a resonant-divergent propagator theory. In the present work we do, however, observe noticeable relativistic corrections to the Verdet constant in the off-resonant regions for systems with light elements (F2 and Cl2), and nonrelativistic results for the Verdet constant of Br2 are in error by 25% in the low-frequency region." @default.
- W2010381158 created "2016-06-24" @default.
- W2010381158 creator A5034879764 @default.
- W2010381158 creator A5037324451 @default.
- W2010381158 creator A5056711547 @default.
- W2010381158 date "2005-02-10" @default.
- W2010381158 modified "2023-10-16" @default.
- W2010381158 title "Four-component Hartree–Fock calculations of magnetic-field induced circular birefringence—Faraday effect—in noble gases and dihalogens" @default.
- W2010381158 cites W1978978917 @default.
- W2010381158 cites W1994253622 @default.
- W2010381158 cites W1999326405 @default.
- W2010381158 cites W2017344081 @default.
- W2010381158 cites W2022459586 @default.
- W2010381158 cites W2023037821 @default.
- W2010381158 cites W2034894909 @default.
- W2010381158 cites W2052312990 @default.
- W2010381158 cites W2063546960 @default.
- W2010381158 cites W2066975750 @default.
- W2010381158 cites W2069852362 @default.
- W2010381158 cites W2070528546 @default.
- W2010381158 cites W2073974973 @default.
- W2010381158 cites W2077524557 @default.
- W2010381158 cites W2090634772 @default.
- W2010381158 cites W2090898907 @default.
- W2010381158 cites W2143981217 @default.
- W2010381158 cites W2179747560 @default.
- W2010381158 cites W4231266850 @default.
- W2010381158 cites W4240035468 @default.
- W2010381158 cites W4243928810 @default.
- W2010381158 doi "https://doi.org/10.1063/1.1849167" @default.
- W2010381158 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15743246" @default.
- W2010381158 hasPublicationYear "2005" @default.
- W2010381158 type Work @default.
- W2010381158 sameAs 2010381158 @default.
- W2010381158 citedByCount "7" @default.
- W2010381158 countsByYear W20103811582012 @default.
- W2010381158 countsByYear W20103811582013 @default.
- W2010381158 countsByYear W20103811582015 @default.
- W2010381158 countsByYear W20103811582020 @default.
- W2010381158 crossrefType "journal-article" @default.
- W2010381158 hasAuthorship W2010381158A5034879764 @default.
- W2010381158 hasAuthorship W2010381158A5037324451 @default.
- W2010381158 hasAuthorship W2010381158A5056711547 @default.
- W2010381158 hasConcept C104416048 @default.
- W2010381158 hasConcept C115260700 @default.
- W2010381158 hasConcept C121332964 @default.
- W2010381158 hasConcept C184779094 @default.
- W2010381158 hasConcept C203734380 @default.
- W2010381158 hasConcept C207230154 @default.
- W2010381158 hasConcept C3079626 @default.
- W2010381158 hasConcept C62520636 @default.
- W2010381158 hasConceptScore W2010381158C104416048 @default.
- W2010381158 hasConceptScore W2010381158C115260700 @default.
- W2010381158 hasConceptScore W2010381158C121332964 @default.
- W2010381158 hasConceptScore W2010381158C184779094 @default.
- W2010381158 hasConceptScore W2010381158C203734380 @default.
- W2010381158 hasConceptScore W2010381158C207230154 @default.
- W2010381158 hasConceptScore W2010381158C3079626 @default.
- W2010381158 hasConceptScore W2010381158C62520636 @default.
- W2010381158 hasIssue "7" @default.
- W2010381158 hasLocation W20103811581 @default.
- W2010381158 hasLocation W20103811582 @default.
- W2010381158 hasOpenAccess W2010381158 @default.
- W2010381158 hasPrimaryLocation W20103811581 @default.
- W2010381158 hasRelatedWork W1979906671 @default.
- W2010381158 hasRelatedWork W1980934368 @default.
- W2010381158 hasRelatedWork W2007855090 @default.
- W2010381158 hasRelatedWork W2020386230 @default.
- W2010381158 hasRelatedWork W2023601804 @default.
- W2010381158 hasRelatedWork W2094847165 @default.
- W2010381158 hasRelatedWork W2264114546 @default.
- W2010381158 hasRelatedWork W2323491721 @default.
- W2010381158 hasRelatedWork W3143856854 @default.
- W2010381158 hasRelatedWork W4240651181 @default.
- W2010381158 hasVolume "122" @default.
- W2010381158 isParatext "false" @default.
- W2010381158 isRetracted "false" @default.
- W2010381158 magId "2010381158" @default.
- W2010381158 workType "article" @default.