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- W2010395849 abstract "The adsorption of carbon monoxide on the Ir(110) surface at 300 K has been investigated with Fourier transform infrared reflection-absorption spectroscopy. A single band was observed that shifted up from a low-coverage value of 2001 cm−1 to a saturation-coverage limit of 2086 cm−1. This band is attributed to the carbon-oxygen stretching mode of a molecule adsorbed on top of a surface iridium atom. This frequency shift was separated into a contribution due to dipole-dipole interactions and a smaller contribution from chemical effects (d-electron competition) by using isotopic substitution. Employing knowledge of the structure of the reconstructed Ir(110) surface and temperature-programmed desorption spectra measured at various coverages, an adlayer model is proposed to reconcile a single adsorption site with the temperature-programmed desorption data." @default.
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- W2010395849 date "1995-02-01" @default.
- W2010395849 modified "2023-10-18" @default.
- W2010395849 title "Adsorption of carbon monoxide on Ir(110) investigated by infrared reflection-absorption spectroscopy" @default.
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- W2010395849 doi "https://doi.org/10.1016/0039-6028(94)00729-2" @default.
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