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- W2010406659 abstract "Abstract The title compound, the first member of a homologous series of oligomers formed by free radical polymerization of methyl methacrylate initiated by tetraphenylbutanedinitrile, was synthesized and its structure was determined by X-ray diffraction. The longest CC bond of this molecule measures 1.628 A and can be thermally split to give radicals. The activation energy of this dissociation was found to be 150 kJ/mol. The kinetics of the free radical polymerization of methyl methacrylate and styrene initiated with the title compound shows remarkable deviations from the ideal polymerization kinetics, indicating that primary radical termination might be the main chain termination reaction." @default.
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- W2010406659 title "Initiation of polymerization with substituted ethanes—12. Free radical polymerization of methyl methacrylate and styrene initiated with 3-methoxycarbonyl-3-methyl-2,2,5,5-tetraphenylhexanedinitrile" @default.
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- W2010406659 doi "https://doi.org/10.1016/0014-3057(89)90037-2" @default.
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