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- W2010407566 abstract "Abstract The Pd‐mediated Buchwald–Hartwig amination reaction of aryl halides in a phosphonium salt ionic liquid consisting of a trihexyl(tetradecyl)phosphonium cation with a range of anions has been investigated. A pronounced anionic effect was uncovered with the reaction proceeding readily with weakly nucleophilic diarylamines only in the presence of noncoordinating anions. A mechanism is postulated to explain these results and it involves a rate‐limiting ligand exchange step that proceeds through a dissociative pathway.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W2010407566 date "2007-03-01" @default.
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- W2010407566 title "A Pronounced Anionic Effect in the Pd‐Catalyzed Buchwald–Hartwig Amination Reaction Revealed in Phosphonium Salt Ionic Liquids" @default.
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- W2010407566 doi "https://doi.org/10.1002/ejoc.200700005" @default.
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