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- W2010409912 abstract "Abstract Smectic lipid-water systems were macroscopically oriented between glass slides. Lipids used were dimyristoyllecithin, potassium oleate, and potassium linolate. Proton spectra of hitherto unattained resolution were observed when these lipid model membranes were oriented at the magic angle. The T 1 value of resolved resonances was measured as a function of temperature at 100 and 360 MHz. The residual linewidth at the magic angle orientation is determined by the inherent anisotropy of diamagnetic susceptibility in lipid bilayers. The T 2 value of the methylene resonance in the potassium oleate-water system was evaluated from a saturation study. The conclusion from these experiments is that the model membrane is a two-dimensional fluid; the molecular motion is a plane perpendicular to the bilayer normal is characterized by a single correlation time of the order of 10 −10 sec. Dimyristoyllecithin was also investigated in vesicle form; T, values and activation energies differ from the multilayer results but most of the discrepancy can be ascribed to the different water contents of the two systems." @default.
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- W2010409912 date "1981-03-01" @default.
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- W2010409912 title "Proton relaxation measurements on lipid membranes oriented at the magic angle" @default.
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- W2010409912 doi "https://doi.org/10.1016/0022-2364(81)90263-8" @default.
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