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• W2010410542 abstract "Interactions of dissolved organic matter (DOM) with clays can significantly affect a variety of soil processes. We studied adsorption and fractionation of hydrophobic acid (HoA) and hydrophobic neutral (HoN) fractions of DOM on Cu2+- and Fe3+-montmorillonite. Adsorption of both samples was higher on Fe3+-montmorillonite than on Cu2+-montmorillonite. A pH increase of about one unit was recorded followed by HoA adsorption by Fe3+-montmorillonite. This suggested exchange of negatively charged DOM groups on surface hydroxyl groups of Fe3+-montmorillonite surfaces. Adsorption of HoA on Cu2+-montmorillonite and HoN on Fe3+- and Cu2+-montmorillonites was governed mainly by van der Waals interactions. Spectroscopic analyses showed a distinct HoA fractionation by molecular size and aromaticity only by Fe3+-montmorillonite. On the basis of the pH measurements (increase in pH following adsorption of acid components) and enhanced DOM fractionation by molecular size and aromaticity we suggest that DOM reacted with Fe3+-montmorillonite similar to goethite." @default.
• W2010410542 created "2016-06-24" @default.
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• W2010410542 date "2008-05-21" @default.
• W2010410542 modified "2023-10-11" @default.
• W2010410542 title "Interactions of Hydrophobic Fractions of Dissolved Organic Matter with Fe³⁺- and Cu²⁺-Montmorillonite" @default.
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• W2010410542 doi "https://doi.org/10.1021/es8003602" @default.
• W2010410542 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18678008" @default.
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