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• W2010415712 abstract "We present here the synthesis of hierarchical calcite, grown in the presence of acidic glycoproteins isolated from adult spines of the sea urchin Evechinus chloroticus. Hierarchical growth is only achieved when kinetic growth control (attained for high concentrations of calcium ion) is superimposed on the thermodynamic constraints imposed by crystal growth under limiting carbon dioxide in the presence of glycoproteins. Cleaved oligosaccharides produce analogous hierarchical structures, suggesting that they provide a similar growth environment for the calcium carbonate as the parent glycoproteins. Their effect is achieved at lower concentration as compared with the glycoproteins. Deglycosylated protein does not produce this effect and at high concentrations completely inhibits calcium carbonate growth." @default.
• W2010415712 created "2016-06-24" @default.
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• W2010415712 date "2004-01-01" @default.
• W2010415712 modified "2023-09-29" @default.
• W2010415712 title "Superimposed effect of kinetics and echinoderm glycoproteins on hierarchical growth of calcium carbonate" @default.
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• W2010415712 doi "https://doi.org/10.1039/b312126g" @default.
• W2010415712 hasPublicationYear "2004" @default.
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