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• W2010426566 abstract "Co K-edge X-ray absorption near-edge spectra at 300K and magnetic studies for the rhombohedral LaCoO3 with low-spin state to intermediate-spin (IS) state transition Ts≃105K and orthorhombic EuCoO3(Ts≃295K) are reported. The small pre-edge feature observed is from 1s–3d dipole transition, which is weakly allowed through the hybridization of Co 4p states with 3d states of neighboring Co atoms. For both samples in the IS state, pre-edge can be fitted using three peaks with energy separation P2−P1=2.0eV for R=La and Eu, and P3−P2=1.5eV for R=La and 1.3eV for R=Eu. Since the thermally excited IS state is a mixed t2g5eg1 and d7L̄(t2g6eg1 or t2g5eg2), with almost filled t2g↑ states. From reported band structure calculation, the three peaks P1, P2, P3 are probably corresponding to the unfilled t2g↓, eg↑ and eg↓ states, respectively." @default.
• W2010426566 created "2016-06-24" @default.
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• W2010426566 date "2003-05-01" @default.
• W2010426566 modified "2023-10-17" @default.
• W2010426566 title "Co K-edge XANES and spin-state transition of RCoO3 (R=La, Eu)" @default.
• W2010426566 cites W1990138025 @default.
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• W2010426566 doi "https://doi.org/10.1016/s0921-4526(02)02595-4" @default.
• W2010426566 hasPublicationYear "2003" @default.
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