FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2010435538> ?p ?o ?g. }

• W2010435538 endingPage "8613" @default.
• W2010435538 startingPage "8607" @default.
• W2010435538 abstract "The combination of the Knudsen cell with a standard cubic ICR trapping cell produces a number of cluster ions of molybdenum oxides MoxOy+ (x = 1−5, y = 1−15). Ionization of molybdenum trioxide vapors by electron impact yields MoxOy+ with high oxygen-to-metal ratios. Collisions with vacuum gas lead to reduction of oxygen-saturated molybdenum oxide cluster ions and to fragmentation of MoxOy+ ions with x > 3, whereas dimers and trimers are relatively stable. Time and temperature dependencies of MoxOy+ concentrations suggested that Mo4O12+ and Mo5O15+ are the primary products of MoO3 vaporization and other ions are the products of their fragmentation. A simple pair-potential model was used to calculate energy-optimized geometric structures of the clusters. The model identifies the most abundant clusters as having the lowest calculated energy per atom. The six-ring Mo3O9 cluster was found to be the most stable species, and molybdenum oxides with four and five metal atoms also include the six atom ring where one or two oxygen atoms are substituted for the MoO3 group. Ion−molecular reactions of molybdenum oxide cluster ions with some small molecules have been studied. MoxOy+ ions readily oxidize the CO molecule to CO2. Reactions of MoxOy+ ions with cyclopropane occur through the activation of the C−C bond of cyclopropane. In general, different molybdenum oxides exhibit the same reactivity toward c-C3H6. Dimer and trimer ions undergo the ligand-exchange reactions with ammonia, and molybdenum oxide trimers Mo3O8+ and Mo3O9+ dehydrogenate the NH3 molecule, yielding a complex with nitrogen." @default.
• W2010435538 created "2016-06-24" @default.
• W2010435538 creator A5030049942 @default.
• W2010435538 creator A5039410192 @default.
• W2010435538 creator A5046769968 @default.
• W2010435538 creator A5075659782 @default.
• W2010435538 date "1997-11-01" @default.
• W2010435538 modified "2023-09-27" @default.
• W2010435538 title "Molybdenum Oxide Cluster Ions in the Gas Phase: Structure and Reactivity with Small Molecules" @default.
• W2010435538 cites W1971346964 @default.
• W2010435538 cites W1982367837 @default.
• W2010435538 cites W1983728059 @default.
• W2010435538 cites W1987499453 @default.
• W2010435538 cites W2003190003 @default.
• W2010435538 cites W2004623596 @default.
• W2010435538 cites W2011664369 @default.
• W2010435538 cites W2014576173 @default.
• W2010435538 cites W2021523869 @default.
• W2010435538 cites W2021911678 @default.
• W2010435538 cites W2030815596 @default.
• W2010435538 cites W2033644685 @default.
• W2010435538 cites W2036522350 @default.
• W2010435538 cites W2036821779 @default.
• W2010435538 cites W2043913000 @default.
• W2010435538 cites W2047897552 @default.
• W2010435538 cites W2053514515 @default.
• W2010435538 cites W2059730328 @default.
• W2010435538 cites W2066650182 @default.
• W2010435538 cites W2067062830 @default.
• W2010435538 cites W2067843071 @default.
• W2010435538 cites W2079745964 @default.
• W2010435538 cites W2082940460 @default.
• W2010435538 cites W2086221032 @default.
• W2010435538 cites W2088389259 @default.
• W2010435538 cites W2094551660 @default.
• W2010435538 cites W2921323522 @default.
• W2010435538 cites W2949694966 @default.
• W2010435538 doi "https://doi.org/10.1021/jp971585v" @default.
• W2010435538 hasPublicationYear "1997" @default.
• W2010435538 type Work @default.
• W2010435538 sameAs 2010435538 @default.
• W2010435538 citedByCount "62" @default.
• W2010435538 countsByYear W20104355382012 @default.
• W2010435538 countsByYear W20104355382013 @default.
• W2010435538 countsByYear W20104355382014 @default.
• W2010435538 countsByYear W20104355382016 @default.
• W2010435538 countsByYear W20104355382017 @default.
• W2010435538 countsByYear W20104355382018 @default.
• W2010435538 countsByYear W20104355382019 @default.
• W2010435538 countsByYear W20104355382020 @default.
• W2010435538 countsByYear W20104355382021 @default.
• W2010435538 countsByYear W20104355382022 @default.
• W2010435538 crossrefType "journal-article" @default.
• W2010435538 hasAuthorship W2010435538A5030049942 @default.
• W2010435538 hasAuthorship W2010435538A5039410192 @default.
• W2010435538 hasAuthorship W2010435538A5046769968 @default.
• W2010435538 hasAuthorship W2010435538A5075659782 @default.
• W2010435538 hasConcept C142724271 @default.
• W2010435538 hasConcept C145148216 @default.
• W2010435538 hasConcept C178790620 @default.
• W2010435538 hasConcept C179104552 @default.
• W2010435538 hasConcept C185592680 @default.
• W2010435538 hasConcept C204787440 @default.
• W2010435538 hasConcept C2776403692 @default.
• W2010435538 hasConcept C2776910235 @default.
• W2010435538 hasConcept C2779200411 @default.
• W2010435538 hasConcept C2779546866 @default.
• W2010435538 hasConcept C2779851234 @default.
• W2010435538 hasConcept C2780378348 @default.
• W2010435538 hasConcept C32909587 @default.
• W2010435538 hasConcept C549387045 @default.
• W2010435538 hasConcept C62396407 @default.
• W2010435538 hasConcept C71924100 @default.
• W2010435538 hasConcept C75473681 @default.
• W2010435538 hasConceptScore W2010435538C142724271 @default.
• W2010435538 hasConceptScore W2010435538C145148216 @default.
• W2010435538 hasConceptScore W2010435538C178790620 @default.
• W2010435538 hasConceptScore W2010435538C179104552 @default.
• W2010435538 hasConceptScore W2010435538C185592680 @default.
• W2010435538 hasConceptScore W2010435538C204787440 @default.
• W2010435538 hasConceptScore W2010435538C2776403692 @default.
• W2010435538 hasConceptScore W2010435538C2776910235 @default.
• W2010435538 hasConceptScore W2010435538C2779200411 @default.
• W2010435538 hasConceptScore W2010435538C2779546866 @default.
• W2010435538 hasConceptScore W2010435538C2779851234 @default.
• W2010435538 hasConceptScore W2010435538C2780378348 @default.
• W2010435538 hasConceptScore W2010435538C32909587 @default.
• W2010435538 hasConceptScore W2010435538C549387045 @default.
• W2010435538 hasConceptScore W2010435538C62396407 @default.
• W2010435538 hasConceptScore W2010435538C71924100 @default.
• W2010435538 hasConceptScore W2010435538C75473681 @default.
• W2010435538 hasIssue "46" @default.
• W2010435538 hasLocation W20104355381 @default.
• W2010435538 hasOpenAccess W2010435538 @default.
• W2010435538 hasPrimaryLocation W20104355381 @default.
• W2010435538 hasRelatedWork W1988597001 @default.
• W2010435538 hasRelatedWork W2030687189 @default.
• W2010435538 hasRelatedWork W2065339948 @default.

• next