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• W2010445038 abstract "Tetramolecular G-quadruplexes result from the association of four guanine-rich strands. Modification of the backbone strand or the guanine bases of the oligonucleotide may improve stability or introduce new functionalities. In this regard, the 8 position of a guanosine is particularly suitable for introduction of modifications since as it is positioned in the groove of the quadruplex structure. Modifications at this position should not interfere with structural assembly as would changes at Watson–Crick and Hoogsteen sites. In this study, we investigated the effect of an 8-methyl-2′-deoxyguanosine residue (M) on the structure and stability of tetramolecular parallel G-quadruplexes. In some cases, the presence of this residue resulted in the formation of unusual quadruplex structures containing all-syn tetrads. Furthermore, the modified nucleoside M at the 5′-end of the sequence accelerated quadruplex formation by 15-fold or more relative to the unmodified oligonucleotide, which makes this nucleobase an attractive replacement for guanine in the context of tetramolecular parallel quadruplexes." @default.
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• W2010445038 date "2011-03-01" @default.
• W2010445038 modified "2023-09-27" @default.
• W2010445038 title "Effects of 8-methylguanine on structure, stability and kinetics of formation of tetramolecular quadruplexes" @default.
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• W2010445038 doi "https://doi.org/10.1016/j.biochi.2010.10.011" @default.
• W2010445038 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21034790" @default.
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