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• W2010450950 endingPage "2059" @default.
• W2010450950 startingPage "2049" @default.
• W2010450950 abstract "We report a nitrogen adsorption isotherm study on three shale samples that have been previously characterized by small-angle neutron scattering (SANS). The scattering data establish that the pore surfaces in these porous materials are self-similar fractals over a range of length scales between 5 and 500 AA{}, and the fractal dimension D varies between 2.59 and 2.83. For isothermal adsorption of multilayer liquid film on fractal surfaces, the theoretical predictions are (i) the number of adsorbed molecules N increases with the vapor pressure P as $Nensuremath{sim}[mathrm{ln}{(P}_{0}/P){]}^{Densuremath{-}3}$ and (ii) the area of the liquid-vapor interface ${S}_{I}$ decreases as ${S}_{I}ensuremath{sim}[mathrm{ln}{(P}_{0}/P){]}^{Densuremath{-}2}.$ We find that fitting our data to these predictions results in D values that are significantly lower than the SANS results. More careful examination of the data reveals systematic deviations from the predicted power-law behaviors. We discuss the assumptions and approximations made in the theories that could have caused this discrepancy." @default.
• W2010450950 created "2016-06-24" @default.
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• W2010450950 date "1999-02-01" @default.
• W2010450950 modified "2023-10-10" @default.
• W2010450950 title "Experimental study of multilayer adsorption on fractal surfaces in porous media" @default.
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• W2010450950 doi "https://doi.org/10.1103/physreve.59.2049" @default.
• W2010450950 hasPublicationYear "1999" @default.
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