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• W2010462024 abstract "Seven compounds of general formula Pd(CNR)(η3-2-XC3H4)[PH3PC(H)COMe]BF4(X = H, R = p-C6H4OMe (1, R = C(Me)3 (2; X = Me, R = p-C6H4OMe (3), C(Me)3 (4), Me (5), C6H11 (6), p-C6H4NO2 (7)) have been prepared by chloride abstraction from PdCl(η3-2-XC3H4)[Ph3PC(H)COMe] (X = H, me) with AgBF4 and subsequent reaction of the cationic intermediate with the appropriate isocyanide ligand. all the complexes have been characterized by analytical and spectroscopic (IR, 1H and 31P1H NMR) data. They have been shown to be a mixture of two diastereoisomeric forms arising from the simultaneous presence on the palladium atom of the asymmetric ylidic carbon atom and the η3-allyl ligand. The determination of the crystal structure of complex 4 showed that in the solid state only one diastereoisomer is present. The crystals are monoclinic, space group Pc with a 9.833(3), b 14.383(4), c 11.762(4) A, β 114.68(3)°, and Z = 2. Final full-matrix least-squares refinement, based on 2413 reflections, converged to R = 0.050. The keto-stabilized ylide ligand is C bonded to the metal with a PdC distance of 2.175 (9) A." @default.
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• W2010462024 date "1989-05-01" @default.
• W2010462024 modified "2023-09-27" @default.
• W2010462024 title "Preparation and characterization of PdIII-ylide complexes of type Pd(CNR)(η3-2-XC3H4)[Ph3PC(H)COMe] BF4 (X = H, Me; R = p-C6H4OMe, C(Me)3, Me, C6H11, p-C6H4NO2). Crystal structure of Pd[CNC(Me)3]-(η3-2-MeC3H4)[Ph3PC(H)COMe] BF4" @default.
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• W2010462024 doi "https://doi.org/10.1016/0022-328x(89)87191-8" @default.
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