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• W2010469488 abstract "Rare earth ion-doped CeO2 has attracted more and more attention because of its special electrical, optical, magnetic, or catalytic properties. In this paper, a facile electrochemical deposition route was reported for the direct growth of the porous Gd-doped CeO2. The formation process of Gd-doped CeO2 composites was investigated. The obtained deposits were characterized by SEM, EDS, XRD, and XPS. The porous Gd3+-doped CeO2 (10 at% Gd) displays a typical type I adsorption isotherm and yields a large specific surface area of 135 m2/g. As Gd3+ ions were doped into CeO2 lattice, the absorption spectrum of Gd3+-doped CeO2 nanocrystals exhibited a red shift compared with porous CeO2 nanocrystals and bulk CeO2, and the luminescence of Gd3+-doped CeO2 deposits was remarkably enhanced due to the presence of more oxygen vacancies. In addition, the strong magnetic properties of Gd-doped CeO2 (10 at% Gd) were observed, which may be caused by Gd3+ ions or more oxygen defects in deposits. In addition, the catalytic activity of porous Gd-doped CeO2 toward CO oxidation was studied." @default.
• W2010469488 created "2016-06-24" @default.
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• W2010469488 date "2009-01-05" @default.
• W2010469488 modified "2023-10-17" @default.
• W2010469488 title "Hierarchically Porous Gd³⁺-Doped CeO₂ Nanostructures for the Remarkable Enhancement of Optical and Magnetic Properties" @default.
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• W2010469488 doi "https://doi.org/10.1021/jp804572t" @default.
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