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- W2010476927 abstract "The sulfidation of calcined limestone and dolomite was studied in an ambient pressure quartz thermogravimetric analyzer (TGA) reactor unit at 982°C. Comparative sulfidation experiments were performed with and without the presence of HCl using both calcined limestone and dolomite in two particle sizes. The reactant gas contained H 2 S, H 2 , H 2 O, and nitrogen. The H 2 S and HCl content of the reactant gas was chosen to represent oxygen-blown and air-blown coal gasification environments. The results of this study indicate that the addition of both steam and HCl enhances the overall rate of sulfidation reaction and that the rate is linearly dependent on the HCl content of the reactant gas up to 100 ppm for limestone and 150 ppm for dolomite. The sulfidation reaction rate is insensitive to HCl concentrations above these levels for these sorbents. The results obtained in this study suggest that the enhancement of the sulfidation reaction rate in the presence of HCl is caused by surface phenomena that are related to the presence of steam." @default.
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- W2010476927 date "1993-08-01" @default.
- W2010476927 modified "2023-09-26" @default.
- W2010476927 title "Effect of HCl on sulfidation of calcium oxide" @default.
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- W2010476927 doi "https://doi.org/10.1016/0009-2509(93)80181-o" @default.
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