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- W2010485719 abstract "Abstract A series of blue dyes, 1,7-diaminoperylene bisimides ( 2a – 2c ), was synthesized under mild condition in high yields, and was characterized by 1 H NMR, UV–Vis, HRMS spectra, cyclic voltammetry, differential scanning calorimetry, and thermogravimetric analyses. These molecules undergo an excited-state intramolecular electron transfer reaction, resulting in a unique charge transfer emission. Upon excitation, they show smaller dipole moment changes than those of the asymmetric 1-aminoperylene bisimides ( 4a – 4c ); the dipole moments of these compounds have been estimated using the Lippert–Mataga equation. Furthermore, they undergo two quasi-reversible one-electron oxidations and two quasi-reversible one-electron reductions in dichloromethane at modest potentials. Their optical properties in various conditions and complementary density functional theory (DFT) calculations are reported." @default.
- W2010485719 created "2016-06-24" @default.
- W2010485719 creator A5040030867 @default.
- W2010485719 creator A5064289848 @default.
- W2010485719 date "2013-02-01" @default.
- W2010485719 modified "2023-09-26" @default.
- W2010485719 title "1,7-Diaminoperylene bisimides: Synthesis, optical and electrochemical properties" @default.
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- W2010485719 doi "https://doi.org/10.1016/j.dyepig.2012.09.003" @default.
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