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- W2010491502 abstract "Ion binding properties of antamanide-like cyclopeptides cyclo-(Pro2–Glyn-Pro2–Glym) (n, m = 1–3) have been studied by CD spectroscopy and by conductivity measurements. Cyclo-(Pro2–Gly-Pro2–Gly) forming complexes of different stoichiometry can be characterized by a strong preference of selectivity for Mg++ and Ca++ ions over alkali ions whereas the other members of the series bind selectively alkali and alkaline earth cations with ion radius of about 1 Å. Three main types of CD spectra of cyclic peptides and their complexes can be differentiated. Type I showing two negative Cotton effects at around 220 nm and 200 nm (Ib, Fig. 3), type II showing a positive band around 220 nm and a strong negative one below 190 nm (e.g. Ic in acetonitrile, Fig. 4), and type III showing a strong negative band in the 205 nm region (e.g. metal complexes of Id, Fig. 6)." @default.
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- W2010491502 date "2009-01-12" @default.
- W2010491502 modified "2023-10-15" @default.
- W2010491502 title "ION BINDING PROPERTIES IN ACETONITRILE OF CYCLO-PEPTIDES BUILT UP FROM PROLINE AND GLYCINE RESIDUES" @default.
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- W2010491502 doi "https://doi.org/10.1111/j.1399-3011.1977.tb02805.x" @default.
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