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- W2010496713 abstract "1-Methyl-5-mercapto-tetrazole (mmtz) reacts with Co(II) salts in the presence of N-containing ligands and three CoII/CoIII complexes, [CoII(mmtz)2(4,4′-bipy)(H2O)2] n (1), [CoIII(mmtz)2(1,10-phen)2]NO3 (2), and [(mmtz)2(2,2′-bipy)2(μ-OH)2]Cl2 (3), have been characterized using single-crystal X-ray diffraction structure determination, IR, and elemental analysis. Complex 1 has a 1-D polymeric structure with neutral [Co(mmtz)2(4,4′-bipy)(H2O)2] as repeating unit. These 1-D infinite chains are further connected into a 3-D supramolecular framework through intermolecular hydrogen bonds. In 2, mmtz is an S-bonding ligand to form a mononuclear structure. In 3, mmtz as a μ 2 bridging ligand links Co(III) ions to form a dimeric structure. Thermostability of 2 and 3 and electrochemical properties of 1–3 are discussed." @default.
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- W2010496713 date "2012-09-06" @default.
- W2010496713 modified "2023-09-26" @default.
- W2010496713 title "Three Co<sup>II</sup>/Co<sup>III</sup> complexes with a 1-substituted tetrazole-5-thiol ligand" @default.
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- W2010496713 doi "https://doi.org/10.1080/00958972.2012.723205" @default.
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