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- W2010507094 abstract "Abstract Most oximes as well as their N-alkyl and O-alkyl derivatives are electrochemically reduced in a single four-electron step to the amine. Some exceptions have been reported, where the reduction occurs in two two-electron steps. The reduction of the O-methyloxime grouping in the antibiotic cefetamet occurs at pH 5–9 in two steps, corresponding to a reduction to the imine and amine, respectively. It has been shown that the separation of the two two-electron processes is caused by differences in position and rate of establishment of acid–base equilibria resulting in protonations of the oxime and imino grouping." @default.
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- W2010507094 date "2001-07-01" @default.
- W2010507094 modified "2023-09-26" @default.
- W2010507094 title "Two-step reduction of the O-methyloxime group in the antibiotic cefetamet" @default.
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- W2010507094 doi "https://doi.org/10.1016/s0022-0728(01)00507-1" @default.
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