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- W2010509868 abstract "Knudsen cell mass spectrometry was performed on vapors from a sample containing NaAlCl4(l) and NaCl(s) at an average temperature of 500 K. The vapor was analyzed using electron bombardment with 50 eV electrons. Several ions were detected which permitted the conclusion that the vapor consisted of AlCl3, Al2Cl6, NaAlCl4, and Na2Al2Cl8. Ion intensities were determined as a function of the temperature of the vapor in the Knudsen cell. Data were treated thermodynamically using the van’t Hoff equation. Statistical mechanical calculations were performed for NaAlCl4(g). The data yielded the following thermodynamic data: standard enthalpy of formation at 500 K of NaAlCl4(g), −997.8±6.0 kJ/mol; standard enthalpy of formation at 298.15 K of NaAlCl4(g), −994.8±8.0 kJ/mol; standard enthalpy of formation at 500 K of Na2Al2Cl8(g), −2174.7±8.0 kJ/mol." @default.
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- W2010509868 date "1987-07-01" @default.
- W2010509868 modified "2023-09-23" @default.
- W2010509868 title "Mass spectrometry of and standard enthalpies of formation of gaseous sodium tetrachloroaluminate and its dimer" @default.
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- W2010509868 doi "https://doi.org/10.1063/1.453560" @default.
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