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- W2010511919 endingPage "1803" @default.
- W2010511919 startingPage "1795" @default.
- W2010511919 abstract "One dihydropyrene–thiophene and a series of three dihydropyrene–phenylenevinylene copolymers were synthesized in this work. The core dihydropyrene unit was shown to remain intact in the polymer backbone by 1H NMR studies. Thermal studies indicated higher stability of the dihydropyrene unit in the copolymers compared with the parent molecule, with one of the dihydropyrene–phenylenevinylene copolymers exhibited a single-step onset degradation temperature at 400 °C. Extended conjugation effect in the copolymers was evident based on spectroscopic analysis despite a mismatch of macrocyclic dihydropyrene units and small conjugation partners (thiophene and phenylenevinylene). The copolymers exhibited relatively small bandgaps. All four copolymers exhibit blue light emission in photoluminescence studies. Their emission spectra are essentially identical, suggesting that their emission properties were dominated by the dihydropyrene chromophore but independent of the spacer group (thiophene or phenylenevinylene). © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1795–1803, 2009" @default.
- W2010511919 created "2016-06-24" @default.
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- W2010511919 date "2009-02-24" @default.
- W2010511919 modified "2023-09-26" @default.
- W2010511919 title "Effect of higher nonbenzenoids in optical properties of dihydropyrene–thiophene and dihydropyrene–phenylenevinylene copolymers" @default.
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- W2010511919 doi "https://doi.org/10.1002/pola.23279" @default.
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