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- W2010520478 abstract "Abstract β‐Amino‐α,α‐difluoro ketones have been very conveniently prepared in a one‐pot procedure from acylsilanes, trifluoromethyltrimethylsilane and imines. The key intermediate in this reaction is a difluoroenoxysilane. The Lewis acid promoted imino aldol reaction was performed with BF 3 · OEt 2 or under very mild conditions using a catalytic amount of Yb(OTf) 3 . The reaction with chiral benzylimines occurred in good yield with 52–78 % de . Palladium‐catalyzed hydrogenolysis furnished an unprotected β‐amino‐α,α‐difluoro ketone or a β‐amino‐α,α‐difluoro alcohol. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
- W2010520478 created "2016-06-24" @default.
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- W2010520478 date "2005-10-01" @default.
- W2010520478 modified "2023-09-27" @default.
- W2010520478 title "Mild Synthesis of β‐Amino‐α,α‐difluoro Ketones from Acylsilanes and Trifluoromethyltrimethylsilane in a One‐Pot Imino Aldol Reaction" @default.
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- W2010520478 doi "https://doi.org/10.1002/ejoc.200500106" @default.
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