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- W2010537112 abstract "The conductivities of ternary mixtures of equimolar solutions of iodine and various pyridines were determined at 298 K in ortho-dichlorobenzene and in nitrobenzene. The concentrations of the binary solutions were of the order of 10−2 mole 1−1, In dichlorobenzene a maximum of conductivity appears when the volume fraction YA of the iodine solution lies near 0.67. In nitrobenzene this maximum occurs at YA 0.57 but the latter value increases when the concentrations of the binary mixtures become greater. Taking into account the predominant formation of 1/1 complexes, these results indicate that near the vicinity of the maximal conductivity there is a predominancy of the homoconjugated ions py2I+ and T5− with, in nitrobenzene, a non negligible contribution of the I3−, ions. These deductions are corroborated by the quantitative comparison of the conductivities with the real concentrations of the complexes and of the non-complexed molecules computed from the experimental complexation constant. From these data the addition constant k2− of I2 to the I3− ion is also deduced. The order of magnitude of k2− is 850 l mole in ortho-dichlorobenzene but it falls to 225 1 mole−1 in nitrobenzene, as a consequence of the higher electron acceptor character of this solvent which competes with iodine." @default.
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- W2010537112 date "2010-09-01" @default.
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- W2010537112 title "Homoconjugation of the Ions in Ternary Mixtures Iodine-Pyridines-Dichlorobenzene and Iodine-Pyridines-Nttrobenzene" @default.
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- W2010537112 doi "https://doi.org/10.1002/bscb.19750841005" @default.
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