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- W2010542015 abstract "Single crystals of NH4Er(PO3)4 polyphosphate have been prepared by the flux method and its structural and physical properties have been investigated. This compound crystallizes in the monoclinic system, with space group P21/n and the following parameters: a = 10.259(3) Å, b = 8.884(3) Å, c = 10.910(3) Å, β = 106.27(1)°, V = 954.5(5) Å3 and Z = 4. Its structure is characterized by PO4 phosphate groups which are assembled through common vertices to form (PO3)n spiral chains running along the [1 0 1] direction. These chains are linked to each other by ErO8 polyhedra through common corners. In such a way the resulting 3D framework forms large tunnels, parallel to the [1 0 0] direction, where the NH4+ ions are located. Raman and FT-IR spectra have been registered and discussed. Absorption, excitation and emission spectra of NH4Er(PO3)4 have been investigated for the first time: they show bands characteristics of the Er3+ ions. Decay curves for 2H11/2, 4S3/2 and 4F9/2 levels of Er3+ ion have also been studied." @default.
- W2010542015 created "2016-06-24" @default.
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- W2010542015 creator A5062200272 @default.
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- W2010542015 date "2014-11-01" @default.
- W2010542015 modified "2023-10-17" @default.
- W2010542015 title "Structural study and spectroscopic properties of NH4Er(PO3)4" @default.
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- W2010542015 doi "https://doi.org/10.1016/j.jallcom.2014.05.213" @default.
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