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- W2010552307 abstract "Tl(Bi)-Sr-Ca-Cu-O corresponding to nominal compositions Tl:Bi:Sr:Ca:Cu=(2-x):x:2:2:3 (where x=0.2, 0.4, 0.6 and 1) and Tc ranging between approximately 77 K and approximately 106 K have been synthesized and their structural characteristic explored employing the technique of transmission electron microscopy. An interesting result arising from structural explorations in the present investigation is the presence of a new disordered superstructure a approximately=4.2 AA, c approximately=15.26 AA) embedded in the main monolayer Tl-0, 1212/1223-type structural matrix. Although the new disordered superstructural phase is present for all the compositions studied, its density was found to be highest for the nominal composition Tl1.6Bi0.4Sr2Ca2Cu3O10. This also corresponds to the highest Tc approximately 106 K HTS (high-temperature superconductor) material. It has been suggested that the substitution of Bi for Tl produces disorder through the occurrence of a lone pair on Bi3+. Besides the creation of disorder, the presence of Bi3+ may also lead to the optimization of carrier concentration and hence Tc." @default.
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- W2010552307 date "1991-10-01" @default.
- W2010552307 modified "2023-10-08" @default.
- W2010552307 title "Electron microscope studies of structural characteristics of Tl(Bi)-Sr-Ca-Cu-O high temperature superconductor" @default.
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- W2010552307 doi "https://doi.org/10.1088/0953-2048/4/10/007" @default.
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