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- W2010561824 abstract "The electric birefringence properties of intact bacteriophage T7 DNA are investigated as a function of field strength and ionic environment. At low field strengths, E < 40 V/cm, Kerr behavior is observed. The birefringence decay kinetics are consistent with a Gaussian chain viscoelastic treatment for an induced dipole model of orientation. The observed relaxation time for the longest mode is 37 msec, in 0.5 mM Na+ at 15°C, and is in agreement with flow experiments. In order to account for the observed differences in rise and decay kinetics, a field-induced, anharmonic restoring force is postulated. The magnitude of the apparent induced dipole moment is found to be inversely proportional to the Debye-Hückel shielding parameter κ for a series of Na+ concentrations. The magnitude of the induced dipole moment is found to be very sensitive to the addition of Mg2+. When analyzed in terms of the counterion condensation theory of Manning, it appears that the induced dipole moment is proportional to the square of the reduced effective DNA charge density." @default.
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- W2010561824 date "1979-11-01" @default.
- W2010561824 modified "2023-09-27" @default.
- W2010561824 title "Transient electric birefringence of T7 viral DNA" @default.
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- W2010561824 doi "https://doi.org/10.1002/bip.1979.360181110" @default.
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